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首页> 外文期刊>Langmuir: The ACS Journal of Surfaces and Colloids >Fabrication of centimeter-sized single-domain two-dimensional colloidal crystals in a wedge-shaped cell under capillary forces
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Fabrication of centimeter-sized single-domain two-dimensional colloidal crystals in a wedge-shaped cell under capillary forces

机译:毛细作用下楔形细胞中厘米级单畴二维胶体晶体的制备

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Self-assembly of colloidal spheres confined within cells of different shapes formed with two slides under capillary forces are studied. It is found that by controlling the shape of the cell the curvature of the drying front can result in a significant effect on the self-organization process. A curved drying front formed within parallel slides is always associated with growth of colloidal crystal structures with a high density of disorder. We demonstrate that single-domain two-dimensional colloidal crystals with centimeter size can be grown under capillary forces under a straight drying front formed, in a wedge-shaped cell. These findings are demonstrated by laser diffraction, microscopy imaging methods and off-normal optical transmission measurements. The present growth method should be of importance in expanding colloidal crystal applications in angle-resolved nanosphere lithography, as well as in preparation of high-quality quasi-three-dimensional plasmonic crystals.
机译:研究了在毛细管力作用下,由两个载玻片形成的不同形状的细胞内胶体球的自组装。发现通过控制泡孔的形状,干燥前沿的曲率可以对自组织过程产生显着影响。在平行滑片内形成的弯曲干燥前沿总是与具有高无序密度的胶体晶体结构的生长相关。我们证明具有厘米大小的单域二维胶体晶体可以在楔形细胞中形成的笔直干燥前沿下的毛细管力作用下生长。这些发现通过激光衍射,显微成像方法和非正常的光透射率测量得到证明。目前的生长方法对于扩大角分辨纳米球光刻胶体晶体的应用以及制备高质量准三维等离激元晶体具有重要意义。

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