Synthesis of Allyl Carbamates through the Regioselective Domino Reaction of Amines, CO2, and Unsymmetrical Allyl Chlorides under Pd Catalysis

摘要

The regioselective domino reaction of CO2 (1 atm), amines, and unsymmetrical allyl chlorides in the presence of a palladium complex and K3PO4 under mild conditions to provide allyl carbamates in good yields with excellent regioselectivity (99:1) was accomplished.