A Robust, Well-Defined Homogeneous Silver(I) Catalyst for Mild Intramolecular Hydroamination of 2-Ethynylanilines Leading to Indoles

James McNulty; Kunal Keskar

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A Robust, Well-Defined Homogeneous Silver(I) Catalyst for Mild Intramolecular Hydroamination of 2-Ethynylanilines Leading to Indoles

机译：稳健，定义良好的均相银（I）催化剂，用于2-乙炔苯胺的轻度分子内加氢胺化反应，生成吲哚

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摘要

A highly efficient, chemically stable and well-defined homogeneous silver(I) catalyst is reported for the room temperature, intramolecular hydroamination of 2-alkynylanilines leading to indole derivatives

机译：据报道，在室温下2-炔基苯胺的分子内加氢胺化反应可得到吲哚衍生物，该化合物高效，化学稳定且定义明确，均质银（I）催化剂

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《European journal of organic chemistry》 |2014年第8期|共8页
作者
James McNulty; Kunal Keskar;
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正文语种 eng
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关键词
Homogeneous catalysis; Silver catalysis; Alkynes; Hydroamination;

机译：均相催化;银催化;炔烃;氢化;

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1. A Robust, Well-Defined Homogeneous Silver(I) Catalyst for Mild Intramolecular Hydroamination of 2-Ethynylanilines Leading to Indoles [J] . James McNulty, Kunal Keskar European journal of organic chemistry . 2014,第8期

机译：稳健，定义良好的均相银（I）催化剂，用于2-乙炔苯胺的轻度分子内加氢胺化反应，生成吲哚
2. Intramolecular hydroamination with homogeneous zinc catalysts: Evaluation of substituent effects in N,N '-disubstituted aminotroponiminate zinc complexes [J] . Dochnahl M, Lohnwitz K, Pissarek JW, Chemistry: A European journal . 2007,第23期

机译：用均相锌催化剂进行分子内加氢胺化：评估N，N'-二取代的氨基对亚硝基锌络合物中取代基的作用
3. Intramolecular hydroamination of aminoalkynes with silver-phenanthroline catalysts [J] . Carney JM, Donoghue PJ, Wuest WM, Organic letters . 2008,第17期

机译：银-菲咯啉催化剂对氨基炔的分子内加氢胺化
4. One-Pot Synthesis of Indole Derivatives Using Homogeneous and Polymer-Supported Heterogeneous Palladium Catalysts [C] . Ken Tsutsumi, Hayato Sakai, Tsumoru Morimoto Symposium on Organometallic Chemistry . 2006

机译：使用均相和聚合物负载的非均相钯催化剂单罐合成吲哚衍生物
5. Intramolecular alkene hydroaminations mediated by simple group 3 metal complexes: The development of non-lanthanocene-based catalysts. [D] . Kim, Young Kwan. 2003

机译：简单的第3组金属配合物介导的分子内烯烃加氢胺化：非镧系茂基催化剂的发展。
6. Zirconium Bis(Amido) Catalysts for Asymmetric Intramolecular Alkene Hydroamination [O] . Donald A. Watson, Melanie Chiu, Robert G. Bergman -1

机译：锆双（酰胺基）不对称分子内烯烃加氢胺化催化剂
7. Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes [O] . Daven Foster, Pengchao Gao, Ziyun Zhang, 2021

机译：高活性和选择性手性NHC-铱催化剂的设计，范围和机理，用于各种未致死的氨基烯烃的分子内水氨基

A Robust, Well-Defined Homogeneous Silver(I) Catalyst for Mild Intramolecular Hydroamination of 2-Ethynylanilines Leading to Indoles

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