Ultrathin SnO2 Nanorods: Template- and Surfactant-Free Solution Phase Synthesis, Growth Mechanism, Optical, Gas-Sensing, and Surface Adsorption Properties

摘要

A novel template- and surfactant-free low temperature solution-phase method has been successfully developed for the controlled synthesis of ultrathin SnO2 single-crystalline nanorods for the first time. The ultrathin SnO2 single-crystalline nanorods are 2.0 +/- 0.5 nm in diameter, which is smaller than its exciton Bohr radius. The ultrathin SnO2 nanorods show a high specific area (191.5 m(2) g(-1)). Such a thin SnO2 single-crystalline nanorod is new in the family of SnO2 nanostrucures and presents a strong quantum confinement effect. Its formation depends on the reaction temperature as well as on the concentration of the urea solution. A nonclassical crystallization process, Ostwald ripening process followed by an oriented attachment mechanism, is proposed based on the detailed observations from a time-dependent crystal evolution process. Importantly, such structured SnO2 has shown a strong structure-induced enhancement of gas-sensing properties and has exhibited greatly enhanced gas-sensing property for the detection of ethanol than that of other structured SnO2, Such as the powders of nanobelts and microrods. Moreover, these ultrathin SnO2 nanorods exhibit excellent ability to remove organic pollutant in wastewater by enormous surface adsorption. These properties are mainly attributed to its higher surface-to-volume ratio and ultrathin diameter. This work provides a novel low temperature, green, and inexpensive pathway to the synthesis of ultrathin nanorods, offering a new material form for sensors, solar cells, catalysts, water treatments, and other applications.