A novel 9-MC-3 and 15-MC-6 onset stacked metallacrown single-molecule magnet: Synthesis and crystal structure

Wang S.; Kong L.; Yang H.; He Z.; Jiang Z.; Li D.; Zeng S.; Niu M.; Song Y.; Dou J.

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >A novel 9-MC-3 and 15-MC-6 onset stacked metallacrown single-molecule magnet: Synthesis and crystal structure

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A novel 9-MC-3 and 15-MC-6 onset stacked metallacrown single-molecule magnet: Synthesis and crystal structure

机译：一种新型的9-MC-3和15-MC-6起始堆叠金属lac单分子磁体：合成和晶体结构

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A novel enneanuclear manganese complex, [Mn_9O _4(Mesao)_6(MeO)_3(O_2CMe) _3(OH)(MeOH)_2]?2.5DMF [1; Me-saoH_2 = 2-hydroxyphenylethanone oxime], was synthesized. The structure of 1 contains an unusual [Mn_9O_4] core with an unprecedented defective "supertetrahedron" topology based on two parallel, onset stacked 9-MC-3 and 15-MC-6 metallacrown subunits. Magnetic studies indicate that 1 behaves as a single-molecule magnet.

机译：一种新型的锰锰络合物，[Mn_9O _4（Mesao）_6（MeO）_3（O_2CMe）_3（OH）（MeOH）_2]≥2.5DMF[1;合成了Me-saoH_2 ＝ 2-羟基苯基乙酮肟。 1的结构包含一个不寻常的[Mn_9O_4]核，该核具有前所未有的有缺陷的“超四面体”拓扑，该拓扑基于两个平行的，起始的堆叠9-MC-3和15-MC-6金属漆lac子单元。磁性研究表明1表现为单分子磁体。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2011年第7期|共3页
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Wang S.; Kong L.; Yang H.; He Z.; Jiang Z.; Li D.; Zeng S.; Niu M.; Song Y.; Dou J.;
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1. A novel 9-MC-3 and 15-MC-6 onset stacked metallacrown single-molecule magnet: Synthesis and crystal structure [J] . Wang S., Kong L., Yang H., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第7期

机译：一种新型的9-MC-3和15-MC-6起始堆叠金属lac单分子磁体：合成和晶体结构
2. Synthesis, crystal structure and magnetism of a single-molecule magnet, [Mn16O16(OMe)(6)(OAc)(16)(MeOH)(3)(H2O)(3)] center dot 6H(2)O, and of a mixed bridge 1D chain, [Mn(mu-OMe)(mu-OAc)(2)](n) [J] . Price DJ, Batten SR, Moubaraki B, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第26期

机译：单分子磁体[Mn16O16（OMe）（6）（OAc）（16）（MeOH）（3）（H2O）（3）]中心点6H（2）O的合成，晶体结构和磁性混合桥一维链[Mn（mu-OMe）（mu-OAc）（2）] [n]
3. Synthesis, crystal structure and magnetic properties of novel Mn-12 single-molecule magnets with thiophenecarboxylate, [Mn12O12(O2CC4H3S)(16)(H2O)(4)], and its tetraphenylphosphonium salt [J] . Kuroda-Sowa T., Nogami T., Konaka H., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2003,第14a17期

机译：新型带噻吩羧酸盐的Mn-12单分子磁体[Mn12O12（O2CC4H3S）（16）（H2O）（4）]及其四苯基phosph盐的合成，晶体结构和磁性
4. Automated Synthesis of Hetero-Multinuclear Metal Clusters by Robot Platform and Discovery of New Single-Molecule Magnets [C] . Takuo Minato, Daniel Salley, Leroy Cronin 日本化学会春季年会講演予稿集 . 2018

机译：机器人平台和新型单分子磁体的发现自动合成异核 - 多核金属簇
5. Utilizing metallacrowns to develop new single-molecule magnets. [D] . Zaleski, Curtis M. 2005

机译：利用金属催乳剂开发新的单分子磁体。
6. Synthesis and crystal structure of a pentacopper(II) 12-metallacrown-4: cis-diaquatetrakis(dimethylformamide-κO)manganese(II) tetrakis(μ3-N2-dioxidobenzene-1-carboximidate)pentacopper(II) dimethylformamide monosolvate [O] . Gerard P. Van Trieste III, Matthias Zeller, Curtis M. Zaleski 2020

机译：五铜（II）12-金属lac-4的合成和晶体结构：顺式-二水四（五甲基-N2-二氧代苯-1-羧甲酸酯）五铜（II）二甲基甲酰胺单溶剂化物
7. New single-molecule magnet based on Mn12 oxocarboxylate clusters with mixed carboxylate ligands, Mn12O12(CN-o-C6H4CO2)12(CH3CO2)4(H2O)4·8CH2Cl2: Synthesis, crystal and electronic structure, magnetic properties [O] . L. A. Kushch, V. D. Sasnovskaya, A. I. Dmitriev, 2012

机译：基于Mn12氧化羧酸盐的新型单分子磁体，其中混合羧酸盐配体，Mn12O12（CN-O-C6H4CO2）12（CH 3 CO 2）4（H2O）4·8CH2CL2：合成，晶体和电子结构，磁性

A novel 9-MC-3 and 15-MC-6 onset stacked metallacrown single-molecule magnet: Synthesis and crystal structure

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