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Theory of Nonstationary Diffusion Growth of Gas Bubble in the Supersaturated Solution of Gas in Liquid

机译:液体中气体过饱和溶液中气泡的非稳态扩散生长理论

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摘要

General theory of nonstationary diffusion growth of gas bubble in the supersaturated solution of gas in liquid is constructed using the ideas of similarity and self-similar solutions. The balance between the number of gas molecules in solution and in the bubble that displaces incompressible liquid solvent with an increase in bubble size is taken into account at the material isolation of the solution and the bubble. The dependences of the rate of growth of bubble radius on the solubility of gas and the supersaturation of solution are found. The nonstationary effect of a rapid increase in the rate of bubble growth with an increase in the product of gas solubility and solution supersaturation is elucidated. The upper limit of this product at which bubble growth can be considered as isothermal process is established. The theory is constructed at the arbitrary gas solubility.
机译:利用相似和自相似解的思想,构造了气体在液体过饱和溶液中气泡的非平稳扩散增长的一般理论。在溶液和气泡的材料隔离时,考虑了溶液中和气泡中的气体分子数量之间的平衡,该气泡随着气泡尺寸的增加而置换了不可压缩的液体溶剂。发现气泡半径增长速率对气体溶解度和溶液过饱和度的依赖性。阐明了气泡生长速率快速增加以及气体溶解度和溶液过饱和度乘积增加的非平稳效应。确定了该产品的上限,在该上限处可以将气泡生长视为等温过程。该理论是在任意气体溶解度下构建的。

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