Formation of a Dinuclear Mercury(II) Complex with a Regular Bis-Strapped Porphyrin Following a Tunable Cooperative Process

摘要

The richness of metalloporphyrin chemistry is an important source of innovative features which justifies active investigation of their coordination properties towards post-transition elements.Mercury(II) complexation by porphyrins was first motivated by the observation of its catalytic effect on the complexation of other elements (Cu, Zn) and regained attention in view of the sensing of toxicological organo-mercury(II) compounds.