ORGANOMETALLIC CLUSTER COMPLEXES WITH FACE-CAPPING ARENE LIGANDS .7. NUCLEOPHILIC SUBSTITUTION OF FLUORIDE IN A FACIALLY COORDINATED ARENE LIGAND

Wadepohl H.; Pritzkow H.; Borchert T.

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ORGANOMETALLIC CLUSTER COMPLEXES WITH FACE-CAPPING ARENE LIGANDS .7. NUCLEOPHILIC SUBSTITUTION OF FLUORIDE IN A FACIALLY COORDINATED ARENE LIGAND

机译：带有覆盖面的芳烃配体的有机簇复合物.7。局部配位的芳烃配体中氟化物的核取代

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Reaction of p-fluoro-alpha-methylstyrene with [(eta-C5H5)Co(eta-C(6)Me(6))] leads to the cluster complex [{(eta-C5H5)Co}(3)(mu(3)-eta(2):eta(2):eta(2)-p-fluoro-alpha-methylstyrene )] 1b. Nucleophilic substitution of fluoride by H- or Ph(-) takes place when Ib is treated with LiHBEt(3) or PhLi. [References: 26]

机译：对氟-α-甲基苯乙烯与[[eta-C5H5）Co（eta-C（6）Me（6））]的反应生成簇络合物[{（eta-C5H5）Co}（3）（mu（ 3）-eta（2）：eta（2）：eta（2）-对氟-α-甲基苯乙烯）] 1b。当用LiHBEt（3）或PhLi处理Ib时，氟化物被H-或Ph（-）亲核取代。 [参考：26]

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《Journal of Organometallic Chemistry》 |1996年第2期|共3页
作者
Wadepohl H.; Pritzkow H.; Borchert T.;
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正文语种 eng
中图分类有机化学;
关键词
Arene clusters; Nucleophilic substitution; Cyclopentadienyl cobalt; Pi-(chlorobenzene)chromium tricarbonyl; Carbanions;

机译：芳烃簇;亲核取代;环戊二烯基钴;Pi-（氯苯）三羰基铬;碳负离子;

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1. ORGANOMETALLIC CLUSTER COMPLEXES WITH FACE-CAPPING ARENE LIGANDS .7. NUCLEOPHILIC SUBSTITUTION OF FLUORIDE IN A FACIALLY COORDINATED ARENE LIGAND [J] . Wadepohl H., Pritzkow H., Borchert T. Journal of Organometallic Chemistry . 1996,第1a2期

机译：带有覆盖面的芳烃配体的有机簇复合物.7。局部配位的芳烃配体中氟化物的核取代
2. Organometallic cluster complexes with face-capping arene ligands, 9~1. Hydrogenation of the side-chain in [{(C_5H_5)Co}_3(#mu#_3-alkenylbenzene)]: [{(C_5H_5)Co}_3(#mu#_3-#eta#~2:#eta#~2:#eta#~2-C_6H_5-CHR~1-CH_2R~2)]~2 [J] . Hubert Wadepohl, Klaus Buchner, Michael Herrmann, Journal of Organometallic Chemistry . 1999,第1a2期

机译：带有封端的芳烃配体的有机金属簇络合物，9〜1。 [{（C_5H_5）Co} _3（＃mu＃_3-链烯基苯）]中侧链的氢化：[{（C_5H_5）Co} _3（＃mu＃_3-＃eta＃〜2：＃eta＃〜2 ：＃eta＃〜2-C_6H_5-CHR〜1-CH_2R〜2）]〜2
3. Electrophilic reactivity of arene ligands coordinated to ruthenium carbido cluster complexes [J] . Borchert T., Raithby PR., Shields GP., Inorganica Chimica Acta . 1998,第2期

机译：芳烃配体的亲电反应与钌碳原子团簇配合物配合使用
4. Cationic Uranium Alkyl Complexes of a Rigid NON-Donor Pincer Ligand: The Impact of Arene-Coordination on Ethylene Polymerization Activity [C] . David J. H. Emslie, N. R. Andreychuk, B. Vidjayacoumar Rare Earth Research Conference . 2019

机译：刚性非供体钳配体的阳离子铀烷基复合物：芳烃配位对乙烯聚合活性的影响
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Influence of the π-coordinated arene on the anticancer activity of ruthenium(II) carbohydrate organometallic complexes [O] . Muhammad Hanif, Samuel M. Meier, Alexey A. Nazarov, 2013

机译：π配位的芳烃对钌（II）碳水化合物有机金属配合物抗癌活性的影响
7. C-H Activation of Arenes and Substituted Arenes by the Yttrium Hydride (Cp*2YH)2: Competition between Cp* Ligand Metalation, Arene Metalation, and H/D Exchange. Molecular Structures of Cp*2Y(μ-H)(μ-η1,η5-CH2C5Me4)YCp* and Cp*2Y(o-C6H4PPh2CH2) [O] . Booij, Martin, Deelman, Berth-Jan, Duchateau, Rob, 1993

机译：氢化钇（Cp * 2YH）2的C-H活化芳烃和取代的芳烃：Cp *配体金属化，芳烃金属化和H / D交换之间的竞争。 Cp * 2Y（μ-H）（μ-η1，η5-CH2C5Me4）YCp *和Cp * 2Y（o-C6H4PPh2CH2）的分子结构

ORGANOMETALLIC CLUSTER COMPLEXES WITH FACE-CAPPING ARENE LIGANDS .7. NUCLEOPHILIC SUBSTITUTION OF FLUORIDE IN A FACIALLY COORDINATED ARENE LIGAND

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