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Viscosity Effects in Rigid PVC

机译:硬质PVC的粘度效应

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摘要

The viscosity of PVC is better understood if the material is trated as a fluid which contains filler. Anomalous effects such as die swell increasing with increasing melt temperature and melting history causing changes to the viscosity can be explained if the PVC primary particles are viewed as filler which disappears during melting. The fusion torque peak is well-described by this approach. The compaction minimum is a free-flowing which changes to a filler-containing viscous liquid. If another viscous liquid is added to a PVC compound, then the fusion peak will be at a lower torque, because the effective level of filler is reduced. This reduction helps to explain the fusion curve of PVC compounds that contain chlorianted polyethylene (CPE) impact modifier.
机译:如果将材料处理为含有填料的流体,则可以更好地理解PVC的粘度。如果将PVC初级颗粒视为在熔融过程中消失的填料,则可以解释异常效应,例如模头膨胀随熔融温度的升高而增加,以及熔融历史导致粘度的变化。该方法很好地描述了融合扭矩峰值。最小压实度是自由流动的,其变为含填料的粘性液体。如果将另一种粘性液体添加到PVC化合物中,则熔融峰将处于较低的扭矩,因为会降低填充剂的有效含量。这种减少有助于解释含有氯化聚乙烯(CPE)抗冲改性剂的PVC化合物的熔融曲线。

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