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Viscosity effects in rigid PVC

机译:刚性PVC中的粘度效应

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The viscosity of PVC is better understood if it is treated as a fluid which contains filler. Anomalous effects such as die swell increasing with increasing melt temperature and melting history causing changes to the viscosity can be explained if the PVC primary particles are viewed as filler which disappears during melting. The fusion torque peak is well described by this approach. The compaction minimum is a free flowing powder which transitions to a filler-containing viscous liquid. If another viscous liquid is added to a PVC compound then the fusion peak will be at a lower torque because the effective level of filler is reduced. This helps to explain the fusion curve of PVC compounds that contain CPE impact modifier.
机译:如果作为含有填料的流体,则更好地理解PVC的粘度。如果PVC初级颗粒被视为在熔化期间消失的填料,可以解释随着熔融温度和熔化史而导致粘度变化的熔融温度和熔化史等异常效果增加。熔化扭矩峰值通过这种方法很好地描述。压实最小值是自由流动的粉末,其转变为含填料的粘性液体。如果将另一种粘性液体加入到PVC化合物中,则熔融峰将处于较低的扭矩,因为减少了有效水平。这有助于解释包含CPE影响改性剂的PVC化合物的融合曲线。

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