Ene reaction with Pummerer-type reaction intermediate of 1-[(2-methylthio)ethanoyl]pyrrolidine: A novel synthesis of trichonine

Sun KH.; Chen LC.; Wang HM.

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Ene reaction with Pummerer-type reaction intermediate of 1-[(2-methylthio)ethanoyl]pyrrolidine: A novel synthesis of trichonine

机译：1-[（（2-甲硫基）乙炔基]吡咯烷的Pummerer型反应中间体的烯类反应：曲古宁的新型合成

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Pummerer-type reaction intermediate 2 of 1-[(2-methylthio)ethanoyl]pyrrolidine (1) has been found to react with 1-alkenes to afford ene adducts 3. Trichonine 4 was synthesized from the adduct 3g. [References: 10]

机译：已经发现1-[（（2-甲硫基）乙酰基]吡咯烷（1）的Pummerer型反应中间体2与1-烯烃反应得到烯加合物3。由加合物3g合成了T碱4。 [参考：10]

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《Journal of the Chinese Chemical Society.》 |1998年第5期|共3页
作者
Sun KH.; Chen LC.; Wang HM.;
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正文语种 eng
中图分类化学;化学工业;
关键词
Pummerer-type reaction intermediate; Phenyliodine(iii) bis(trifluoroacetate); Ene reaction; Amides;

机译：Pummerer型反应中间体;苯基碘（iii）双（三氟乙酸酯）;Ene反应;酰胺;

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1. Ene reaction with Pummerer-type reaction intermediate of 1-[(2-methylthio)ethanoyl]pyrrolidine: A novel synthesis of trichonine [J] . Sun KH., Chen LC., Wang HM. Journal of the Chinese Chemical Society. . 1998,第5期

机译：1-[（（2-甲硫基）乙炔基]吡咯烷的Pummerer型反应中间体的烯类反应：曲古宁的新型合成
2. Ene Reaction with Pummerer-type Reaction Intermediate of #alpha#-(Methylthio)isobutyl Acetamide:A New Synthesis of Pellitorine [J] . Chen Ling-Ching, Kang Iou-Jiun Journal of the Chinese Chemical Society. . 1999,第6期

机译：乙烯反应与#alpha＃-（甲硫基）异丁基乙酰胺的Pummerer型反应中间体的合成
3. Ene reaction of pummerer-type reaction intermediate and synthesis of pellitorine [J] . Lin WS., Chen LC., WAng HM. Journal of the Chinese Chemical Society. . 1998,第1期

机译：pummerer型反应中间体的烯类反应和拼花碱的合成
4. Non-steady-state kinetics of the reactions of electrode generated intermediates. Resolution of the kinetics of proton transfer reactions of methylarene radical cations [C] . Vernon D. Parker, Yixing Zhao, Yun Lu International Symposium on Reactive Intermediates in Organic and Biological Electrochemistry . 2001

机译：电极产生的中间体反应的非稳态动力学。分辨甲基乙烯自由基阳离子质子转移反应的动力学
5. Part One. Scope and application of novel intramolecular ene reactions utilizing allenylsilanes as the ene component. Part Two. Approaches to the synthesis of the magellanane group of Lycopodium alkaloids. [D] . Smith, Daniel T. 1997

机译：第一部分。利用烯丙基硅烷作为烯组分的新型分子内烯反应的范围和应用。第二部分。合成石蒜碱生物碱的麦哲伦基团的方法。
6. The Phenol-ene Reaction: Biaryl Synthesis via Trapping Reactions between HDDA-Generated Benzynes and Phenolics [O] . Juntian Zhang, Dawen Niu, Vincent A. Brinker, -1

机译：酚-烯反应：通过HDDA生成的苯并合物与酚类之间的诱捕反应合成联芳基
7. Synthesis of 4Selenothreofuranose Derivatives via Pummerer-Type Reactions of trans-3,4-Dioxygenated Tetrahydroselenophenes Mediated by a Selenonium Intermediate [O] . -1

机译：通过硒中间体介导的反式-3,4-二氧化四氢硒烯烃的翻转型反应合成4Selenothreofuranose衍生物

Ene reaction with Pummerer-type reaction intermediate of 1-[(2-methylthio)ethanoyl]pyrrolidine: A novel synthesis of trichonine

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