Convenient synthesis of methyl indol-2-ylpropiolate

Daniele Passarella; Giordano Lesma; Maurizio Deleo; Marisa Martinelli; Alessandra Silvani

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Convenient synthesis of methyl indol-2-ylpropiolate

机译：吲哚-2-基丙酸甲酯的便捷合成

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Methyl indol-2-ylpropiolate 1 is synthesized by using a catalyst system of PPh_3-CuI in the presence of K_2CO_3 as base. The procedure appears convenient if compared with Pd-catalyzed cross-coupling reactions. The interest is increased by the use of an alk-1-yne containing an electron-withdrawing group.

机译：在K_2CO_3作为碱的存在下，通过使用PPh_3-CuI催化剂体系合成吲哚-2-基丙酸甲酯1。如果与Pd催化的交叉偶联反应相比，该方法看起来很方便。通过使用含有吸电子基团的1-炔基提高了人们的兴趣。

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《Journal of the Chemical Society, Perkin Transactions 1》 |1999年第19期|共2页
作者
Daniele Passarella; Giordano Lesma; Maurizio Deleo; Marisa Martinelli; Alessandra Silvani;
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中图分类有机化学;
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1. Convenient synthesis of methyl indol-2-ylpropiolate [J] . Daniele Passarella, Giordano Lesma, Maurizio Deleo, Journal of the Chemical Society, Perkin Transactions 1 . 1999,第19期

机译：吲哚-2-基丙酸甲酯的便捷合成
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Convenient synthesis of methyl indol-2-ylpropiolate

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