Electrochemical synthesis and structural characterisation of transition metal complexes with 2, 6-bis(1-salicyloyl-hydrazonoethyl)pyridine, H_4daps

摘要

Neutral manganese, cobalt and nickel complexes of the pentadentate hydrazone 2, 6-bis(1-salicyloylhydrazonoethyl) pyridine (H_4daps) have been prepared by means of electrochemical syntheses. They have been characterized by elemental analyses, IR spectroscopy, fast atom bombardment mass spectrometry (FAB) and magnetic susceptibility measurements. The molecular structures of [Mn(H_2daps)(py)_2] 1, [Co(H_2daps)(py)_2] 2, [Ni_2(H_2daps)_2] centre dot CH_2Cl_2 3, and [Ni(H_2daps)_2(py)_2] centre dot CH_2Cl_2 4 have been determined by X-ray diffraction. Depending on the nature of the metal ion, the dianionic [H_2daps]~(2-) ligand shows different co-ordination modes in these complexes: 1 and 2 are mononuclear with the metal atom in a pentagonal bipyramidal environment, 3 and 4 are binuclear with a helicate structure in which the nickel atoms attain octahedral co-ordination.