Thermal and photo reversible gel-sol transition of azobenzene based liquid crystalline organogel

摘要

Azobenzene based photoresponsive gelator, 1,2-bis[4-(4-(10-decyloxy)phenylazo)]-benzoylhydrazine showing selective gelation in alcoholic solvent is described. Whilst their thermodynamic behaviors are investigated by polarized optical microscopy and differential scanning calorimetry, the related layer arrangement is measured by X-ray diffraction techniques in which the organogel shows monotropic liquid crystalline phase. Present work shows that the non-liquid crystalline gelator can be converted into liquid crystalline organogel in the presence of alcoholic solvent in which the trans-cis isomerization of the azobenzene moiety disrupts the entanglement of gel fibers of self-assembly resulting in gel-sol transition. The present result also shows that the organogel is capable of the thermal and photo induced transition from gel-sol and vice versa.