Crystal structure, characterization and thermoelectric properties of the type-I clathrate Ba_(8-y)Sr_yAl_(14)Si_(32) (0.6≤y≤1.3) prepared by aluminum flux

Roudebush J.H.; Toberer E.S.; Hope H.; Jeffrey Snyder G.; Kauzlarich S.M.

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Crystal structure, characterization and thermoelectric properties of the type-I clathrate Ba_(8-y)Sr_yAl_(14)Si_(32) (0.6≤y≤1.3) prepared by aluminum flux

机译：铝熔剂制备的I型包合物Ba_（8-y）Sr_yAl_（14）Si_（32）（0.6≤y≤1.3）的晶体结构，表征和热电性能

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The title compound was prepared as single crystals using an aluminum flux technique. Single crystal and powder X-ray diffraction indicate that this composition crystallizes in the clathrate type-I structure, space group Pm3n. Electron microprobe characterization indicates the composition to be Ba _(8-y)Sr_yAl_(14.2(2))Si_(31.8(2)) (0.77

机译：使用铝熔剂技术将标题化合物制备为单晶。单晶和粉末X射线衍射表明该组合物在笼形的I型结构空间群Pm3n中结晶。电子探针表征表明其组成为Ba_（8-y）Sr_yAl_（14.2（2））Si_（31.8（2））（0.77

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《Journal of Solid State Chemistry》 |2011年第5期|共10页
作者
Roudebush J.H.; Toberer E.S.; Hope H.; Jeffrey Snyder G.; Kauzlarich S.M.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
12 K structure; Ba8Al16Si30; Clathrate type-I; Inorganic clathrate; Low temperature X-ray diffraction; Thermoelectric properties; Zintl phase;

机译：12 K结构;Ba8Al16Si30;I型包合物;无机包合物;低温X射线衍射;热电性能;Zintl相;

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1. Crystal structure, characterization and thermoelectric properties of the type-I clathrate Ba_(8-y)Sr_yAl_(14)Si_(32) (0.6≤y≤1.3) prepared by aluminum flux [J] . Roudebush J.H., Toberer E.S., Hope H., Journal of Solid State Chemistry . 2011,第5期

机译：铝熔剂制备的I型包合物Ba_（8-y）Sr_yAl_（14）Si_（32）（0.6≤y≤1.3）的晶体结构，表征和热电性能
2. Gallium composition dependence of crystallographic and thermoelectric properties in polycrystalline type-I Ba _8Ga _xSi _(46-x) (nominal x=14-18) clathrates prepared by combining arc melting and spark plasma sintering methods (Conference Paper) [J] . Anno H., Yamada H., Nakabayashi T., Journal of Solid State Chemistry . 2012,第Null期

机译：结合电弧熔化和火花等离子体烧结方法制备的多晶IBa _8Ga _xSi _（46-x）（标称x = 14-18）包合物的晶体学和热电性质的镓组成依赖性（会议论文）
3. Crystallographic, thermoelectric, and mechanical properties of polycrystalline type-I Ba_8Al_(16)Si_(30)-based clathrates [J] . Hiroaki Anno, Masahiro Hokazono, Ritsuko Shirataki, Journal of Materials Science . 2013,第7期

机译：多晶型I Ba_8Al_（16）Si_（30）笼形包合物的晶体学，热电学和机械性能
4. Composition Dependence of Thermoelectric Properties in Polycrystalline Type-I Ba_8Ga_xSi_(46-x) (Nominal x=14-18) Clathrates Prepared by Combining Arc Melting and Spark Plasma Sintering Methods [C] . Hiroaki Anno, Hiroki Yamada, Takahiro Nakabayashi, European Conference on Thermoelectrics . 2012

机译：通过组合电弧熔化和火花等离子体烧结方法制备的多晶型-i Ba_8Ga_xSi_（46-x）（标称X = 14-18）克拉酸盐中的热电性能的构成依赖性
5. Flux growth, characterization, and structure-property relations for inorganic oxide crystals: Lithium triborate, potassium titanyl phosphate and lead titanate. [D] . Huang, Yutung. 1993

机译：无机氧化物晶体的助熔剂生长，表征和结构性质关系：三硼酸锂，磷酸氧钛钾和钛酸铅。
6. Crystal Chemistry and Thermoelectric Properties of Type-I Clathrate Ba8Ni∼3.8SixGe42.2−x (x = 0 10 20 42.2) [O] . Yue Dong, Xueyong Ding, Xinlin Yan, 2018

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7. Synthesis, structure, and high-temperature thermoelectric properties of boron-doped Ba_8Al_(14)Si_(31) clathrate I phases [O] . Condron Cathie L., Kauzlarich Susan M., Ikeda Teruyuki, 2008

机译：硼掺杂Ba_8Al_（14）Si_（31）笼形I相的合成，结构和高温热电性能

Crystal structure, characterization and thermoelectric properties of the type-I clathrate Ba_(8-y)Sr_yAl_(14)Si_(32) (0.6≤y≤1.3) prepared by aluminum flux

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