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Processing and performance of carbon/epoxy multi-scale composites containing carbon nanofibres and single walled carbon nanotubes

机译:包含碳纳米纤维和单壁碳纳米管的碳/环氧多尺度复合材料的加工和性能

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The present paper reports and compares the processing and various properties of carbon/epoxy multi-scale composites developed incorporating vapor-grown carbon nanofibres (VCNFs) and single-walled carbon nanotubes (SWCNTs). CNFs and SWCNTs (0.5–1.5 wt. %) were dispersed within epoxy resin using a combination of ultrasonication and mechanical stirring in the presence of a non-ionic surfactant and the nanomaterial/resin dispersions were used to impregnate carbon fabrics in order to develop multi-scale composites. Various properties of multi-scale composites such as mechanical, dynamic mechanical, thermal transmission and wear performance were characterized and reported. It was observed from the experimental results that SWCNTs needed much longer dispersion treatment as compared to CNFs; however, the improvement in properties in case of CNT based multi-scale composites was also much higher. Incorporation of up to 1.5wt. % ofCNT within carbon/epoxy composites led to improvements of 46 % in elastic modulus, 9 % in tensile strength, 150 % in breaking strain, 170 % in toughness, 95 % in storage modulus (at 25 ℃), 167 % in thermal conductivity and also significant improvements in the wear performance of composites. Additionally, a simplified modeling approach based on the micromechanical equations showed that the multi-scale composites, especially containing SWCNTs, presented elastic modulus very close to the predicted values.
机译:本论文报告并比较了开发的结合了气相生长碳纳米纤维(VCNF)和单壁碳纳米管(SWCNT)的碳/环氧多尺度复合材料的加工工艺和各种性能。在非离子表面活性剂的存在下,通过超声和​​机械搅拌相结合,将CNF和SWCNT(0.5–1.5 wt。%)分散在环氧树脂中,并使用纳米材料/树脂分散体浸渍碳纤维,以开发出多种碳纤维。规模的复合材料。表征并报道了多尺度复合材料的各种性能,例如机械性能,动态机械性能,热传递性能和磨损性能。从实验结果可以看出,与CNF相比,SWCNT需要更长的分散处理。然而,在CNT基多尺度复合材料的情况下,性能的改善也更高。掺入量最高为1.5wt。碳/环氧复合材料中的CNT百分比提高了46%的弹性模量,9%的拉伸强度,150%的断裂应变,170%的韧性,95%的储能模量(在25℃时),热导率167%同时也大大改善了复合材料的磨损性能。此外,基于微机械方程式的简化建模方法表明,多尺度复合材料,尤其是包含SWCNT的复合材料,其弹性模量非常接近预测值。

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