The pressure-amorphized state in zirconium tungstate: a precursor to decomposition

摘要

In contrast to widely accepted view that pressure-induced amorphization arises due to kinetic hindrance of equilibrium phase transitions, here we provide evidence that the metastable pressure-amorphized state in zirconium tungstate is a precursor to decomposition of the compound into a mixture of simple oxides. This is from the volume collapse DeltaV across amorphization, which is obtained for the first time by measuring linear dimensions of irreversibly amorphized samples during their recovery to the original cubic phase upon isochronal annealing up to 1000 K. The anomalously large DeltaV of 25.7 +/- 1.2% being the same as that expected for the decomposition indicates that this amorphous state is probably a precursor to kinetically hindered decomposition. A P-T diagram of the compound is also proposed. [References: 27]