A new palladium(II) complex of a functionalized N-heterocyclic carbene: Synthesis, characterization and application in Suzuki-Miyaura cross-coupling reactions

Linninger CS; Herdtweck E; Hoffmann SD; Herrmann WA; Kuhn FE

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A new palladium(II) complex of a functionalized N-heterocyclic carbene: Synthesis, characterization and application in Suzuki-Miyaura cross-coupling reactions

机译：一种功能化的N-杂环卡宾的新型钯（II）配合物：铃木-宫浦的交叉偶联反应的合成，表征和应用

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trans-[PdBr2(NHC)Im] was prepared by reacting the corresponding imidazolium (Im) salt with palladium(H) acetate in dimethylsulfoxide in an in-situ reaction without generating a free carbene. Both the salt and the complex were characterized spectroscopically and by X-ray structure analysis. The complex was tested in homogeneous Suzuki-Miyaura cross-coupling reactions.

机译：反式-[PdBr2（NHC）Im]是通过使相应的咪唑盐（Im）与乙酸钯（H）在二甲基亚砜中进行原位反应而制备的，而不会产生游离的卡宾。盐和配合物都通过光谱和X射线结构分析进行了表征。在均相的Suzuki-Miyaura交叉偶联反应中测试了该络合物。

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《Journal of Molecular Structure》 |2008年第3期|共6页
作者
Linninger CS; Herdtweck E; Hoffmann SD; Herrmann WA; Kuhn FE;
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正文语种 eng
中图分类分子结构;
关键词
Imidazolium salt; N-heterocyclic carbene; Palladium; Suzuki-Miyaura cross-coupling;

机译：咪唑鎓盐;N-杂环卡宾;钯;铃木宫浦交叉偶联;

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1. A new palladium(II) complex of a functionalized N-heterocyclic carbene: Synthesis, characterization and application in Suzuki-Miyaura cross-coupling reactions [J] . Linninger CS, Herdtweck E, Hoffmann SD, Journal of Molecular Structure . 2008,第1a3期

机译：一种功能化的N-杂环卡宾的新型钯（II）配合物：铃木-宫浦的交叉偶联反应的合成，表征和应用
2. Synthesis, characterization and X-ray structures of N-heterocyclic carbene palladium complexes based on calix[4]arenes: highly efficient catalysts towards Suzuki-Miyaura cross-coupling reactions [J] . Hui Ren, Yong Xu, Erwann Jeanneau, Tetrahedron . 2014,第17期

机译：基于杯[4]芳烃的N-杂环卡宾钯配合物的合成，表征和X射线结构：铃木-宫浦交叉偶联反应的高效催化剂
3. Synthesis of novel N-heterocyclic carbene-oxazoline palladium complexes and their applications in suzuki-miyaura cross-coupling reaction [J] . Gu P., Xu Q., Shi M. Synlett . 2013,第10期

机译：新型N-杂环卡宾-恶唑啉钯配合物的合成及其在铃木宫浦交叉偶联反应中的应用
4. Synthesis of Nickel(II) N-Heterocyclic Carbene (NHC) Complexes, Catalyzing Cross-coupling Reactions [C] . Kouki Matsubara, Keita Ueno Symposium on Organometallic Chemistry . 2006

机译：合成镍（II）正杂环基石（NHC）复合物，催化交叉偶联反应
5. Part I: Microwave-Assisted Continuous Flow Organic Synthesis (MACOS) and the Heck-type aminocarbonylation of aryl halides, and, the Suzuki-Miyaura cross-coupling of chloroformates. Part II: Structure-activity relationship (SAR) analysis of NHC-palladium PEPPSI complexes in aminations and cross-couplings [D] . Nasielski, Joanna 2009

机译：第一部分：微波辅助连续流动有机合成（MACOS）和芳基卤化物的Heck型氨基羰基化，以及氯甲酸酯的Suzuki-Miyaura交叉偶联。第二部分：胺和交叉偶联中NHC-钯PEPPSI复合物的结构-活性关系（SAR）分析
6. Palladium(ii)-Acetylacetonato Complexes with Mesoionic Carbenes: Synthesis Structures and Their Application in the Suzuki-Miyaura Cross Coupling Reaction [O] . Lara Hettmanczyk, Bianca Schmid, Stephan Hohloch, 2016

机译：钯（ii）-乙酰丙酮基甲磺酸盐与中等离子的复合物：合成结构及其在铃木-宫浦交叉偶联反应中的应用
7. Inside Back Cover: Palladium(II) Complexes with Small N-Heterocyclic Carbene Ligands as Highly Active Catalysts for the Suzuki-Miyaura Cross-Coupling Reaction (ChemCatChem 5/2013) [O] . Michał S. Szulmanowicz, Andrzej Gniewek, Wojciech Gil, 2013

机译：内盖：钯（II）配合物，具有小的N-杂环丁烯配体作为铃木 - 宫系交叉偶联反应的高活性催化剂（Chemcatchem 5/2013）

A new palladium(II) complex of a functionalized N-heterocyclic carbene: Synthesis, characterization and application in Suzuki-Miyaura cross-coupling reactions

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