Hybrid molecular materials based on organic molecules and the inorganic magnetic cluster [M-4(H2O)(2)(PW9O34)(2)](10-) (M2+ = Co, Mn)

摘要

The synthesis and physical characterization of new organic-inorganic hybrids formed by conducting and magnetic networks are reported. The crystalline radical salts are formed by BEDT-TTF type donors as the organic part, and by large metal-oxide clusters of the type [M-4(H2O)(2)(PW9O34)(2)](10-)(M2+ = Co, Mn) as the inorganic part. We also show how these magnetic clusters can be incorporated in conducting organic polymers to give hybrid organic-inorganic films. [References: 23]