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Chirality of self-assembled metal-semiconductor nanostructures

机译:自组装金属半导体纳米结构的手性

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Plasmonic nanoparticle (NP) chiral dimers are fabricated using different types of homogenous materials. However, the effect of semiconductor nanoscale dimers is unknown. This paper describes the chiroptical effect of different plasmonic metal-semiconductor hybrid nanostructures composed of gold (Au), silver (Ag) NPs and quantum dots (QDs). Three types of DNA-mediated high yield dimers were obtained, which had a distinct diverse chiroptical effect of peak position and intensity. The semiconductor QDs dimers showed a weak CD signal at 600 nm, while enhanced signals were observed after coupling with Au or Ag NPs. This interesting chiroptical effect, which originated from the assembled chiral geometry, provides a new route for further chiral structures fabrication and applications.
机译:等离子纳米粒子(NP)手性二聚体是使用不同类型的均质材料制造的。然而,半导体纳米级二聚体的作用是未知的。本文描述了由金(Au),银(Ag)NP和量子点(QD)组成的不同等离激元金属-半导体杂化纳米结构的整脊效应。获得了三种类型的DNA介导的高产二聚体,它们具有峰位置和强度的独特的手性效应。半导体QD二聚体在600 nm处显示较弱的CD信号,而与Au或Ag NP偶联后观察到增强的信号。这种有趣的手足按摩作用源于组装的手性几何结构,为进一步的手性结构制造和应用提供了一条新途径。

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