Probing the validity of average Hamiltonian theory for spin I=1, 3/2 and 5/2 nuclei by analyzing a simple two-pulse sequence

摘要

in this work, we investigate the accuracy of controlling spin I = 1, 3/2 and 5/2 spin systems by average Hamiltonian theory. By way of example, we consider a simple two-pulse echo sequence and compare this perturbation scheme to a numerical solution of the Von Neumann equation. For the different values of I, we examine this precision as a function of the quadrupolar coupling as well as various experimental parameters such as the pulse spacing and pulse width. Experiments and simulations on I = 3/2 and I = 5/2 spin systems are presented that highlight a spectral artifact introduced due to finite pulse widths as predicted by average Hamiltonian theory. The control of these spin systems by this perturbation scheme is considered by investigating a phase cycling scheme that suppresses these artifacts to zeroth-order of the Magnus expansion. (c) 2008 Published by Elsevier Inc.