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Detecting spin resonance spectra - detecting spectra of specimens with groups of nuclei of same type using sequence of HF pulses and de-phasing pulse

机译:检测自旋共振谱-使用HF脉冲和相移脉冲序列检测具有相同类型核组的样品的光谱

摘要

A sequence of four high frequency pulses is directed at a specimen. The first, weak pulse is selective for the nuclei of a first group. The second, weak pulse, selective for a second group, transforms the magnetisation of all nuclei into a multiple quanta coherence state. The third, strong pulse induces a correlated z-order state. A dephasing pulse is applied before the fourth, weak pulse which is selective for the first group which it converts into a single quantum coherence state, enabling detection of first group resonance. USE/ADVANTAGE - For detecting nuclear spin resonance spectra of specimens with groups of nuclei of same type. Enables display of only one group's signals.
机译:四个高频脉冲序列指向标本。第一个弱脉冲对第一组细胞核具有选择性。对第二组有选择性的第二个弱脉冲将所有原子核的磁化强度转换为多量子相干态。第三个强脉冲诱发一个相关的z阶状态。在第四弱脉冲之前施加移相脉冲,该弱脉冲对第一组具有选择性,然后转换为单个量子相干状态,从而能够检测第一组共振。使用/优点-用于检测具有相同类型核群的标本的核自旋共振谱。仅显示一组信号。

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