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High pressure synthesis of thermally stable fine diamond crystals using silicon-carbide and an alloy

机译:使用碳化硅和合金高压合成热稳定的细金刚石晶体

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摘要

In 1993, it was reported that diamond could be synthesized from silicon-carbide in the presence of some metallic solvent-catalysts under high pressure and high temperature [1,2]. The conversion ratio of carbon to diamond is quite high and the diamond crystals are perfect shapes with clear facets, although the grain size is very small [3]. An optical center of 1.68 eV was observed in the diamond crystals, through cathodoluminescence, suggesting that silicon impurity could be doped into the diamond in the process [4]. In this work, fine diamond crystals were synthesized by using a system of SiC and Ni_(70)Mn_(25)Co_5 alloy under high pressure and high temperature, and the effect of the pressure on the diamond yield was investigated. Thermal stability of the crystals was appraised using thermogravimetric analysis.
机译:1993年,据报道,在高压和高温下,在某些金属溶剂催化剂的存在下,可以由碳化硅合成金刚石[1,2]。碳到金刚石的转化率很高,尽管晶粒很小,但金刚石晶体是具有清晰刻面的完美形状[3]。通过阴极发光,在金刚石晶体中观察到的光学中心为1.68 eV,这表明在该过程中可以将硅杂质掺杂到金刚石中[4]。在这项工作中,通过在高温高压下使用SiC和Ni_(70)Mn_(25)Co_5合金系统合成了精细的金刚石晶体,并研究了压力对金刚石产率的影响。使用热重分析评估晶体的热稳定性。

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