Solvothermal syntheses and characterizations of polysulfido-thioantimonate and thioantimonate templated by Co-phen complex cation

Liu Yun; Lu Jialin; Wang Fang; Shen Yali; Tang Chunying; Zhang Yong; Jia Dingxian

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Solvothermal syntheses and characterizations of polysulfido-thioantimonate and thioantimonate templated by Co-phen complex cation

机译：Co-phen络合阳离子为模板的聚硫代-硫代锑酸盐和硫代锑酸盐的溶剂热合成与表征

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Polythioantimonate [Co(phen)(3)][Sb4S5(S4) 2] (1), thioantimonates [Co(phen) 3] 2Sb18S29 (2), and [H3O][Co(phen) 3] SbS4 9H2O (3) were solvothermally prepared using [Co(phen) 3] 2+ as a structure directing agent in different protic solvents, indicating solvent effects on the solvothermal system of Co/ Sb/ S/ phen.

机译：聚硫代锑酸盐[Co（phen）（3）] [Sb4S5（S4）2]（1），硫代锑酸盐[Co（phen）3] 2Sb18S29（2）和[H3O] [Co（phen）3] SbS4 9H2O（3）用[Co（phen）3] 2+作为结构导向剂在不同质子溶剂中的溶剂热制备，表明溶剂对Co / Sb / S / phen的溶剂热体系有影响。

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来源
《Journal of Coordination Chemistry》 |2015年第14期|共13页
作者
Liu Yun; Lu Jialin; Wang Fang; Shen Yali; Tang Chunying; Zhang Yong; Jia Dingxian;
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正文语种 eng
中图分类无机化学;
关键词
Thioantimonate; Cobalt; Solvothermal syntheses; Solvent effect;

机译：硫代锑酸盐;钴;溶剂热合成;溶剂效应;

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1. Solvothermal syntheses and characterizations of polysulfido-thioantimonate and thioantimonate templated by Co-phen complex cation [J] . Liu Yun, Lu Jialin, Wang Fang, Journal of Coordination Chemistry . 2015,第13a14期

机译：Co-phen络合阳离子为模板的聚硫代-硫代锑酸盐和硫代锑酸盐的溶剂热合成与表征
2. Solvothermal syntheses and characterization of new thioantimonates [Pr(en)3(H2O)(μ2-SbS4)] and [Gd(en)4]SbS4·0.5en (en = ethylenediamine): The SbS43- anion acting as a bridging ligand to lanthanide complex [J] . Ding-Xian Jia, Jie Deng, Qian-Xin Zhao, Journal of Molecular Structure . 2007,第1a3期

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3. Complexations of Mn(II) with SbS4 and SbS3 ligands: Hydrazine-solvothermal syntheses, crystal structures and photocatalytic properties of manganese thioantimonates [J] . Li Shufen, Han Jingyu, Zhang Limei, Journal of Solid State Chemistry . 2019,第期

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Solvothermal syntheses and characterizations of polysulfido-thioantimonate and thioantimonate templated by Co-phen complex cation

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