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ARENE-RUTHENIUM COMPLEXES IMMOBILIZED ON POLYMERS, CATALYSTS CONSISTING OF THE COMPLEXES, AND PROCESSES FOR ORGANIC SYNTHESES WITH THE SAME
ARENE-RUTHENIUM COMPLEXES IMMOBILIZED ON POLYMERS, CATALYSTS CONSISTING OF THE COMPLEXES, AND PROCESSES FOR ORGANIC SYNTHESES WITH THE SAME
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机译:固定在聚合物上的芳烃-钌络合物,由该络合物组成的催化剂以及使用该络合物进行有机合成的方法
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摘要
A novel polymer-supported arene-ruthenium complex represented by the following formula: CHEM , wherein A represents an organic polymer with a side chain containing an aromatic ring coordinated to Ru, X1 and X2 represent the same or different halogen atoms, and R represents a hydrocarbon group that may have a substituent is provided for use as a catalyst. This novel polymer-supported arene-ruthenium complex and catalyst thereof can be produced by a simple process, are stable and easy to recover, have a high catalytic activity, and can be used for various organic synthesis reactions. Novel methods for an organic synthesis reaction such as ring-opening metathesis reaction of an olefin compound and reduction of a carbonyl group, using the catalyst are provided.
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