SYNTHESIS AND CRYSTAL STRUCTURE OF [ReO(AHP)_2(PPh_3)]Cl (HAHP=2-AMINO-3-HYDROXYPYRIDINE): A NOVEL CATIONIC MONOOXORHENIUM(V) COMPLEX

YISHAN SONG; BING YAN; ZHENXIA CHEN

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SYNTHESIS AND CRYSTAL STRUCTURE OF [ReO(AHP)_2(PPh_3)]Cl (HAHP=2-AMINO-3-HYDROXYPYRIDINE): A NOVEL CATIONIC MONOOXORHENIUM(V) COMPLEX

机译：[ReO（AHP）_2（PPh_3）] Cl（HAHP = 2-氨基-3-羟基吡啶）的合成与晶体结构：新型阳离子单氧杂HEN（V）络合物

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The cationic complex [ReO(ahp)_2(PPh_3)]~+ was isolated as the chloride salt from the reaction of trans-[ReOCl_2(PPh_3)_2] and 2-amino-3-hydroxypyridine (Hahp) in ethanol. Coordination of the chelates only occurs through the amino nitrogen and the phenolate oxygen of ahp~-. The X-ray crystal structure shows a distorted octahedral geometry, in which a phenolate oxygen coordinated trans to the oxo group and the rhenium atom is displaced by 0.2520(1) A out of the mean equatorial plane towards the oxo oxygen.

机译：从反式[ReOCl_2（PPh_3）_2]与2-氨基-3-羟基吡啶（Hahp）在乙醇中的反应中分离出氯化物形式的阳离子络合物[ReO（ahp）_2（PPh_3）]〜+。螯合物的配位仅通过氨氮和氨酚的酚氧发生。 X射线晶体结构显示出扭曲的八面体几何形状，其中酚盐氧配位反式排列成氧代基团，and原子从平均赤道平面向氧代氧基团位移0.2520（1）A。

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《Journal of Coordination Chemistry》 |2004年第16期|共5页
作者
YISHAN SONG; BING YAN; ZHENXIA CHEN;
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正文语种 eng
中图分类无机化学;
关键词
Oxorhenium(V); Cationic; 2-Amino-3-hydroxypyridine; X-ray structure;

机译：Oxorhenium（V）;阳离子;2-氨基-3-羟基吡啶;X射线结构;

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1. SYNTHESIS AND CRYSTAL STRUCTURE OF [ReO(AHP)_2(PPh_3)]Cl (HAHP=2-AMINO-3-HYDROXYPYRIDINE): A NOVEL CATIONIC MONOOXORHENIUM(V) COMPLEX [J] . YISHAN SONG, BING YAN, ZHENXIA CHEN Journal of Coordination Chemistry . 2004,第16期

机译：[ReO（AHP）_2（PPh_3）] Cl（HAHP = 2-氨基-3-羟基吡啶）的合成与晶体结构：新型阳离子单氧杂HEN（V）络合物
2. Synthesis and characterization of oxorhenium(V)-'3+1' mixed thiolate [SNS]/[S] and [ONS]/[S] complexes. Crystal and molecular structures of [ReO(eta (3)-SCH2C5H3NCH2S)(eta(1)-C6H4Br-4-S)], [ReO(eta(3)-SCH2C5H3NCH2O)(eta(1)-C6H4X-4-S)] (X = Cl, OMe), [J] . Chen XY., Babich JW., Zubieta J., Inorganica Chimica Acta . 2000,第1a2期

机译：氧化or（V）-'3 + 1'混合硫醇盐[SNS] / [S]和[ONS] / [S]配合物的合成与表征。 [ReO（eta（3）-SCH2C5H3NCH2S）（eta（1）-C6H4Br-4-S）]，[ReO（eta（3）-SCH2C5H3NCH2O）（eta（1）-C6H4X-4-S）的晶体和分子结构）]（X = Cl，OMe），
3. Synthesis and characterization of oxorhenium-'3 + 1' mixed-thiolate complexes. Crystal and molecular structures of [ReO{#eta#~3-(SCH_2CH_2)_2S}(C_6H_4X-4-CH_2S)] (X = F, Cl, Br, OMe) and of the pendant thiolate compounds [ReO{#eta#~3-(SCH_2CH_2)_2S}- [J] . Kevin P. Maresca, Grant H. Bonavia, John W. Babich, Inorganica Chimica Acta . 1999,第2期

机译：氧化or-'3 +1'混合硫醇盐配合物的合成与表征。 [ReO {＃eta＃〜3-（SCH_2CH_2）_2S}（C_6H_4X-4-CH_2S）]（X = F，Cl，Br，OMe）和侧基硫醇盐化合物[ReO {＃eta＃〜3-（SCH_2CH_2）_2S}-
4. Synthesis of Cationic Alkyl Yttrium Complexes and a Cationic Hydride Yttrium Complex and their Reactivity toward Ketones and Carbon Dioxide [C] . Yumiko Nakajima, Jun Okuda Symposium on Organometallic Chemistry . 2007

机译：阳离子烷基钇配合物的合成及阳离子氢化钇络合物及其对酮和二氧化碳的反应性
5. Synthesis, characterization and crystal structures of homonuclear copper complexes with 1,3-bis(dimethylamino)-2-propanol as ligand. [D] . Zheng, Jian-Chuan. 1993

机译：以1,3-双（二甲基氨基）-2-丙醇为配体的同核铜配合物的合成，表征和晶体结构。
6. Synthesis and characterization of oxorhenium(V)–‘3+1’ mixed thiolate SNS/S and ONS/S complexes. Crystal and molecular structures of ReO(η3-SCH2C5H3NCH2S)(η1-C6H4Br-4-S) ReO(η3-SCH2C5H3NCH2O)(η1-C6H4X-4-S) (X=Cl OMe) ReO(η3-SCH2C5H3NCH2O)(η1-C6H4OCH3-4-CH2S) and ReO(η3-SCH2C5H3NCH2S)(η1-C5H4NH-2-S)Cl [O] . Xiaoyuan Chen, Frank J. Femia, John W. Babich, -1

机译：氧化or（V）– 3 + 1混合硫醇盐SNS / S和ONS / S配合物的合成与表征。 ReO（η3-SCH2C5H3NCH2S）（η1-C6H4Br-4-S）ReO（η3-SCH2C5H3NCH2O）（η1-C6H4X-4-S）（X = ClOMe）ReO （η3-SCH2C5H3NCH2O）（η1-C6H4OCH3-4-CH2S）和ReO（η3-SCH2C5H3NCH2S）（η1-C5H4NH-2-S） Cl
7. Synthesis and characterization of oxorhenium(V)–‘3+1’ mixed thiolate SNS/S and ONS/S complexes. Crystal and molecular structures of ReO(η3-SCH2C5H3NCH2S)(η1-C6H4Br-4-S), ReO(η3-SCH2C5H3NCH2O)(η1-C6H4X-4-S) (X=Cl, OMe), ReO(η3-SCH2C5H3NCH2O)(η1-C6H4OCH3-4-CH2S) and ReO(η3-SCH2C5H3NCH2S)(η1-C5H4NH-2-S)Cl [O] . Xiaoyuan Chen, Frank J Femia, John W Babich, 2000

机译：oxorhenium（v） - '3 + 1'混合硫醇盐SnS / S和ONS / S复合物的合成与表征。 Reo（η3-sch2c5H3NCH2s）（η1-c6h4br-4-s）的晶体和分子结构，Reo（η3-sch2c5h3nch2o）（η1-c6h4x-4-s）（x = cl，ome），reo （η3-SCH2C5H3NCH2O）（η1-C6H4OCH3-4-4-CH2S）和REO（η3-SCH2C5H3NCH2S）（η1-C5H4N-2-S） CL

SYNTHESIS AND CRYSTAL STRUCTURE OF [ReO(AHP)_2(PPh_3)]Cl (HAHP=2-AMINO-3-HYDROXYPYRIDINE): A NOVEL CATIONIC MONOOXORHENIUM(V) COMPLEX

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