Matrix influences on the determination of common ions by using ion chromatography Part 1-determination of inorganic anions

摘要

Ion chromatography is the most popular instrumental analytical method used for the determination of anions and cations in water and wastewater. Isocratic ion chromatography with suppressed conductivity detection is frequently used in laboratories carrying out routine analyses of inorganic anions. The paper presents the results of the research into the influence of selected inorganic anions dominant in environmental samples (Cl ~-, NO _3 ~-, SO _4 ~(2-)) on the possibility of simultaneous determination of F ~-, Cl ~-, NO _2 ~-, NO _3 ~-, PO _4 ~(3-) and SO _4 ~(2-) with the application of this most popular ion chromatography type in standard separation conditions. Four Dionex and four Metrohm anion-exchange columns were tested in standard separation conditions recommended by their manufacturers with both standard solutions and environmental samples with complex matrix.