ANION EXCHANGE SORBENT FOR DETERMINATION OF ORGANIC AND INORGANIC ANIONS BY ION CHROMATOGRAPHY METHOD

摘要

FIELD: chemistry.;SUBSTANCE: anion-exchange sorbent comprises a matrix chemically grafted directly or via a spacer with a tertiary amine group containing polar or charged substituents and a quaternary ammonium functional group comprised in the amine polymer or monomeric amine connected to it by means of a spacer. The general formula of the sorbent corresponds to the formula 1: ; , ;where R1 is either absent (R1=0) or is a spacer; R2 is a spacer; X is a polar or charged substituent; ; ;is a quaternary nitrogen atom that is part of an amine polymer or a monomeric amine. The second version of the sorbent comprises a matrix chemically grafted directly or via a spacer with a quaternary ammonium group containing polar or charged substituents and quaternary ammonium groups of at least one aminopolymer or monomeric amine connected to it by means of different or coincident spacers. The general formula of the sorbent corresponds to the formula 2: ; , ;where R1 is either absent (R1=0) or is a spacer; R2, R3 - different or coincident spacers; X is a polar or charged substituent; ; ;- quaternary nitrogen atoms, which are part of aminopolymers or monomeric amines.;EFFECT: improved operating and chromatographic characteristics of sorbents.;8 cl, 1 dwg, 1 tbl, 17 ex