Samarium diiodide mediated reductive addition reaction of 1-(phenylsulfonylmethyl) benzotriazole and 1-(benzoyloxymethyl) benzotriazole to aldehydes and ketones

Zhifang Li; Yongmin Zhang

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Samarium diiodide mediated reductive addition reaction of 1-(phenylsulfonylmethyl) benzotriazole and 1-(benzoyloxymethyl) benzotriazole to aldehydes and ketones

机译：io二碘化物介导的1-（苯磺酰基甲基）苯并三唑和1-（苯甲酰氧基甲基）苯并三唑对醛和酮的还原加成反应

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摘要

1-(β-hydroxyalkyl) benzotriazoles were prepared via reductive addition reactions of Bt~1CH_2SO_2Ph or Bt~1CH_2OC(O)Ph with aldehydes and ketones under mild conditions promoted by Sml_2.

机译：在Sml_2促进的条件下，通过Bt〜1CH_2SO_2Ph或Bt〜1CH_2OC（O）Ph与醛和酮的还原加成反应制备了1-（β-羟烷基）苯并三唑。

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《Journal of Chemical Research. Synopses》 |2001年第12期|共3页
作者
Zhifang Li; Yongmin Zhang;
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正文语种 eng
中图分类化学;
关键词
samarum diiodide; 1-(β-hydroxyalkyl) benzotriazoles;

机译：刺梨二碘化物;1-（β-羟烷基）苯并三唑;

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专利

1. Samarium diiodide mediated reductive addition reaction of 1-(phenylsulfonylmethyl) benzotriazole and 1-(benzoyloxymethyl) benzotriazole to aldehydes and ketones [J] . Zhifang Li, Yongmin Zhang Journal of Chemical Research. Synopses . 2002,第12期

机译：io二碘化物介导的1-（苯磺酰基甲基）苯并三唑和1-（苯甲酰氧基甲基）苯并三唑对醛和酮的还原加成反应
2. Samarium diiodide mediated reductive addition reaction of 1-(phenylsulfonylmethyl) benzotriazole and 1-(benzoyloxymethyl) benzotriazole to aldehydes and ketones [J] . Zhifang Li, Yongmin Zhang Journal of Chemical Research. Synopses . 2001,第12期

机译：io二碘化物介导的1-（苯磺酰基甲基）苯并三唑和1-（苯甲酰氧基甲基）苯并三唑对醛和酮的还原加成反应
3. The Reductive Addition Reaction of Substituted 2-Chloromethyl-1, 3, 4-oxadiazole to Aldehydes and Ketones Promoted by Samarium Diiodide [J] . Xiao Liang XU, Wei Min ZHU, Yong Min ZHANG 中国化学快报（英文版） . 2005,第012期

机译：取代的2-氯甲基-1,3,4-恶二唑与二碘化Sa促进的醛和酮的还原加成反应
4. Coupling Reaction Between (Haloarene)Tricarbonylchromium Complexes and Benzylic Halides, Mediated by Samarium Diiodide [C] . E. Parlea, S. Rosca, J.L. Namy 12th Romanian International Conference on Chemistry and Chemical Engineering Sep 13-15, 2001 Bucharest, Romania . 2001

机译：二碘化Sa介导的（卤代芳烃）三羰基铬配合物与卤代苯的偶联反应
5. The total synthesis of Rhizoxin D, a samarium diiodide reduction method for beta-hydroxy and beta-alkoxy ketones, and an approach to Epothilone B. [D] . Wager, Carrie Ann. 2000

机译：Rhizoxin D的全合成，β-羟基和β-烷氧基酮的二碘化sa还原方法以及Epothilone B的制备方法。
6. Bis{1-(benzoyloxy)methyl-1H-123-benzotriazole-κN3}(nitrato-κ2OO′)silver(I) [O] . Sen Xu, Yingzhong Shen 2012

机译：双{1-（苯甲酰氧基）甲基 -1H-123-苯并三唑-κN3}（nitrato-κ2OO）银（I）
7. Synthesis of 1-[3-(2-methyl-5-nitro-1H-imidazol-1-yl)propyl]-1H-1,2,3-benzotriazole and 1-[3-(2-methyl-5-nitro-1H-imidazol-1-yl)butyl]-1H-1,2,3-benzotriazole [O] . Maria Grzegożek, Krystyna Nowak, Barbara Szpakiewicz 2006

机译：1- [3-（2-甲基-5-硝基-1H-咪唑-1-基）丙基] -1H-1,2,3-苯并三唑和1- [3-（2-甲基-5-硝基）的合成-1H-咪唑-1-基）丁基] -1H-1,2,3-苯并三唑

Samarium diiodide mediated reductive addition reaction of 1-(phenylsulfonylmethyl) benzotriazole and 1-(benzoyloxymethyl) benzotriazole to aldehydes and ketones

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