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首页> 外文期刊>Journal of Chemical Education >Investigating Friction as a Main Source of Entropy Generation in the Expansion of Confined Gas in a Piston-and-Cylinder Device
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Investigating Friction as a Main Source of Entropy Generation in the Expansion of Confined Gas in a Piston-and-Cylinder Device

机译:研究摩擦作为活塞-汽缸装置中密闭气体膨胀中熵产生的主要来源

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摘要

The expansion or compression of gas confined in a piston-and-cylinder device is a classic working example used for illustrating the First and Second Laws of Thermodynamics. The balance of energy and entropy enables the estimation of a number of thermodynamic properties. The entropy generation (also called entropy production) resulting from this process can also be used to determine the feasibility and reversibility of a process. In this work, we present an extended discussion involving quantitative analysis of the effects of friction between a piston and the interior wall of a cylinder. Our findings indicate that the friction force caused by the movement of the piston is a main source of entropy generation in this process. This explanation does not appear in most textbooks dealing with similar problems. We also discuss, from a quantitative perspective, the effects of friction on the dynamic physical and thermodynamic properties, including entropy generation. Our findings suggest that engaging students in a discussion related to piston-and-cylinder problems involving the effects of friction could provide valuable insight into entropy generation in practical applications.
机译:限制在活塞缸装置中的气体的膨胀或压缩是一个经典的工作示例,用于说明热力学第一定律和第二定律。能量和熵的平衡使得能够估计许多热力学性质。由该过程产生的熵产生(也称为熵产生)也可以用于确定过程的可行性和可逆性。在这项工作中,我们将进行广泛的讨论,其中涉及对活塞与气缸内壁之间的摩擦效果进行定量分析。我们的发现表明,在此过程中,由活塞运动引起的摩擦力是产生熵的主要来源。在大多数涉及类似问题的教科书中都没有出现这种解释。我们还从定量角度讨论了摩擦对动态物理和热力学性质(包括熵产生)的影响。我们的发现表明,让学生参加与涉及摩擦影响的活塞和气缸问题有关的讨论可以为实际应用中的熵产生提供有价值的见解。

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