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Synthesis and crystal structure of Bis-(N,N'-dibenzylethane-1,2-diamine) cobalt(II) acetate

机译:双(N,N'-二苄基乙烷-1,2-二胺)乙酸钴(II)的合成及晶体结构

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摘要

Bis-(N,N'-dibenzylethane-1,2-diamine) cobalt(II) acetate has been synthesized and the crystal structure determined. The compound crystallizes in the space group P2_1/c, a = 8.3212(6) ?, b = 11.8774(8) ?, c = 17.3643(12) ?, β = 98.1850(10)°, V = 1698.7(2) ?~3, Z = 2. The complex occupies a crystallographic inversion center. The cobalt is in a distorted octahedral environment likely due to steric influences of the acetate groups. Graphical Abstract: The compound bis-(N,N'-dibenzylethane-1,2-diamine) cobalt(II) acetate has been synthesized and the crystal structure determined.[Figure not available: see fulltext.]
机译:合成了双(N,N'-二苄基乙烷-1,2-二胺)乙酸钴(II),并确定了晶体结构。该化合物在空间群P2_1 / c中结晶,a = 8.3212(6)δ,b = 11.8774(8)δ,c = 17.3643(12)δ,β= 98.18050(10)°,V = 1698.7(2)δ。 〜3,Z =2。该配合物占据了晶体学反演中心。由于乙酸酯基团的空间影响,钴处于扭曲的八面体环境中。图形摘要:合成了化合物双-(N,N'-二苄基乙烷-1,2-二胺)乙酸钴(II),并确定了晶体结构。[图不可用:见全文。]

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