A supramolecular structure of bis(1,3-diphenyl-1,3-propanedionato-O,O ')(1,10-phenanthroline-N,N ')cobalt(II) based on C-H center dot center dot center dot O, C-H center dot center dot center dot pi and pi center dot center dot center dot pi interact

摘要

The compound bis(1,3-diphenyl-1,3-propanedionato-O,O') (1,10-phenanthroline-N, N')cobalt(II) (Co(DBM)(2)(1,10-phe)) was investigated as a potential host component for functional inclusion materials. The molecules of the complex in the crystal (a=21.015(5) angstrom, b=17.456(5) angstrom, c=9.503(3) angstrom, beta=107.04(2)angstrom, s.g. C 2/c) are centrosymmetric and assemble by way of C-H center dot center dot center dot O and C-H center dot center dot center dot pi hydrogen bonds as well as pi center dot center dot center dot C stacking interactions to provide a supramolecular ladder-like motif that is accompanied by a variant of the six phenyl-embrace synthon.