Separation of cobalt and zinc from concentrated nickel sulfate solutions with Cyanex 272

摘要

Background: Removal of cobalt and zinc from concentrated nickel solutions separately using two Cyanex 272 circuits has been practised in the nickel industry. However, no detailed study has been conducted and data are scarce for further improvement. This study aims to optimise the operating conditions and to simplify the process flowsheet. RESULTS: With a synthetic solution containing 100 g L~(-1) Ni, 1.4 g L~(-1) Co and 0.8 g L~(-1) Zn and the organic solution containing Cyanex 272 and TBP in Shellsol D70, the operating conditions of extraction, scrubbing and stripping were optimised. McCabe-Thiele diagrams were constructed to determine the theoretical extraction and stripping stages and a flowsheet to separate cobalt and zinc from nickel was proposed. With this flowsheet, more than 99% cobalt and zinc could be separated, resulting in a pure nickel solution with less than 10 mg L~(-1) of cobalt and zinc. CONCLUSIONS: The current study shows that Cyanex 272 can be used to separate cobalt and zinc in one Cyanex 272 circuit effectively from concentrated nickel solutions to obtain very pure nickel solutions suitable for nickel electrowinning or hydrogen reduction. The cobalt and zinc in the loaded strip liquor were concentrated over 10 times and can be separated readily in another much smaller solvent extraction circuit.