Experimental Determination of the Vapor - Liquid Equilibrium at 101.32 kPa of the Ternary System 1-Butanol + Methanol + TAME

摘要

Experimental isobaric vapor-liquid equilibrium data are reported at 101.32 kPa for the ternary system 1-butanol + methanol + TAME (2-methoxy-2-methylbutane or tert-amyl methyl ether) and for one unmeasured constituent binary system (TAME + 1-butanol). These data were found to be thermodynamically consistent and were satisfactorily correlated with the Wilson. NRTL, and UNIQUAC equations. They have also been compared with predictions obtained from the application of ASOG and UMIFAC group contribution methods and from the correlation equations using interaction parameters of the dconstituent binary systems.