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Exergy analysis in hydrogen-air detonation

机译:氢-空气爆轰的火用分析

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The main goal of this paper is to analyze the exergy losses during the shock and rarefaction wave of hydrogen-air mixture. First, detonation parameters (pressure, temperature, density, and species mass fraction) are calculated for three cases where the hydrogen mass fraction in air is 1.5, 2.5, and 5. Then, exergy efficiency is used as objective criteria of performance evaluation. A two-dimensional computational fluid dynamic code is developed using Finite volume discretization method coupled with implicit scheme for the time discretization (Euler system equations). A seven-species and five-step global reactions mechanism is used. Implicit total variation diminishing (TVD) algorithm, based on Riemann solver, is solved. The typical diagrams of exergy balances of hydrogen detonation in air are calculated for each case. The energy balance shows a successive conversion of kinetic energy, and total enthalpy, however, does not indicate consequent losses. On the other hand, exergy losses increase with the augment of hydrogen concentration in air. It obtained an exergetic efficiency of 77.2, 73.4 and 69.7 for the hydrogen concentrations of 1.5, 2.5, and 5, respectively.
机译:本文的主要目的是分析氢-空气混合物在冲击波和稀疏波过程中的火用损失。首先,针对空气中氢的质量分数为1.5、2.5和5的三种情况,计算爆炸参数(压力,温度,密度和物质质量分数)。然后,将火用效率用作性能评估的客观标准。使用有限体积离散化方法和隐式方案进行时间离散化(Euler系统方程),从而开发了二维计算流体动力代码。使用了七种五步全局反应机制。求解了基于黎曼求解器的隐式总变化量递减(TVD)算法。计算每种情况下空气中氢爆轰的火用平衡图。能量平衡显示了动能的连续转换,但是总焓并不表示随后的损失。另一方面,随着空气中氢浓度的增加,火用损失增加。氢气浓度分别为1.5、2.5和5时,其能量效率分别为77.2、73.4和69.7。

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