首页> 外文期刊>Journal of Applied Spectroscopy >THEORETICAL STUDY OF SPIN-TEMPERATURE PHENOMENA IN EPR FOR THE LOW-TEMPERATURE APPROXIMATION AND STEADY-STATE CONDITIONS
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THEORETICAL STUDY OF SPIN-TEMPERATURE PHENOMENA IN EPR FOR THE LOW-TEMPERATURE APPROXIMATION AND STEADY-STATE CONDITIONS

机译:EPR中低温近似和稳态条件下自旋温度现象的理论研究

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摘要

Using the concept of spin temperature in EPR in the low-temperature approximation and under steady-state conditions, we examine the dependence of the reciprocal spin temperature of the Zeeman subsystem and the dipole-dipole reservoir on the reciprocal lattice temperature in the presence of a saturating field. We show that more significant cooling of the dipole-dipole reservoir and heating of the Zeeman subsystem can be achieved than in the case of the high-temperature approximation. In the presence of a probe field, we study the conditions for the absorption to go to zero at the frequency of this field, as a function of the intensity of the saturating field and the frequency difference between the two fields. We show that the intensity of the saturating field increases as the frequencies of the fields come closer together, and goes to infinity when they coincide. This qualitatively corresponds to what we have in the case of the high-temperature approximation. The intensity of the saturating field has a minimum in the dependence on detuning of the frequency of the saturating field when the frequency of the probe field is fixed, as in the case of the high-temperature approximation. We can use this dependence to estimate the relaxation parameters.
机译:在低温近似和稳态条件下,使用EPR中的自旋温度概念,我们研究了在存在α原子的情况下,Zeeman子系统和偶极-偶极储层的互逆自旋温度对晶格温度的依赖性。饱和场。我们表明,与高温近似的情况相比,可以实现偶极子-偶极子水库的更大冷却和Zeeman子系统的加热。在存在探测场的情况下,我们研究了在该场频率处吸收达到零的条件,该条件取决于饱和场的强度和两个场之间的频率差。我们表明,饱和场的强度随着场频率的靠近而增加,并且在它们重合时达到无穷大。这在质量上与我们在高温近似情况下的情况相对应。当探测场的频率固定时,饱和场的强度与饱和场的频率失谐有关,这与高温近似的情况一样最小。我们可以使用这种依赖性来估计松弛参数。

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