Radiocarbon reservoir effects in human bone collagen from northern Iceland

摘要

Human bone collagen from a series of Icelandic human pagan graves was radiocarbon (~(14)C) dated to aid understanding of early settlement (landndm) chronologies in northern Iceland. These individuals potentially consumed marine protein. The ~(14)C age of samples containing marine carbon requires a correction for the marine ~(14)C reservoir effect. The proportion of non-terrestrial sample carbon was quantified via measurement of carbon stable isotopes (δ~(13)C) using a simple mixing model, based on δ~(13)C measurements of archaeofaunal samples. Non-terrestrial carbon was also quantified in six pig bones from the archaeofaunal dataset. Assuming all non-terrestrial carbon in human and pig bone collagen was marine-derived, calibrated age ranges calculated using a mixed IntCa109/Marine09 calibration curve were consistent with an early settlement date close to landndm, but several samples returned prelandnam age ranges. Measurements of nitrogen stable isotopes (δ~(15)N) strongly suggest that many of the human bone collagen samples contain freshwater diet-derived carbon. Icelandic freshwater systems frequently display large freshwater ~(14)C reservoir effects, of the order of 10,000 ~(14)C years, and we suggest that the presence of freshwater carbon is responsible for the anomalously early ages within our dataset. In pig samples, the majority of non-terrestrial carbon is freshwater in origin, but in human samples the proportion of freshwater carbon is within the error of the marine component (±10%). This presents a major obstacle to assessing temporal patterns in the ages of human remains from sampled graves, although the majority of grave ages are within the same, broad, calibrated range.