Iron(II)-based catalysts for ethene oligomerization

摘要

The synthesis of iron(II) complexes with various tridentate di(imino)pyridine ligands and their potential as ethene oligomerization catalysts are described. The ligands are characterized by H-1- and C-13-NMR spectroscopy and the complexes only by mass spectrometry due to their paramagnetism. After activation either with methylalumoxane (MAO) or with a heterogeneous cocatalyst consisting of partially hydrolyzed trimethylaluminum and silica gel, the prepared complexes proved to be good catalysts for the oligomerization of ethene. 1-Octene, 1-hexene, and 1-decene were the major products, formed in very high isomeric purity (99.9 %). (C) 2003 Wiley Periodicals, Inc. [References: 27]