DIFFUSE REFLECTANCE FOURIER TRANSFORM INFRARED SPECTRA OF WOOD FIBERS TREATED WITH MALEATED POLYPROPYLENES

摘要

The esterification reaction between wood fibers and maleated polypropylenes was investigated. The reaction was conducted in a reactor in the presence of xylene used as a solvent and sodium hypophosphite as catalyst. The reaction between wood fibers and pure maleic anhydride was also investigated. The appearance of an infrared absorption band near 1730 cm(-1) indicated that maleated polypropylene chemically reacted by esterification with bleached Kraft cellulose. However, no direct evidence of an esterification reaction was obtained between thermomechanical pulp and maleated polypropylene. The Fourier transform infrared (FTIR) studies showed also that both bleached Kraft cellulose and thermomechanical pulp reacted with maleic anhydride with the formation of ester links. (C) 1997 John Wiley & Sons, Inc. [References: 29]