Thermal and crystallization characteristics of poly(ethylene terephthalate) with poly(oxybenzoate-p-trimethylene terephthalate) copolymer

摘要

Poly(ethylene terephthalate) (PET) was blended with two different poly(oxybenzoate-p-trimethylene terephthalate) copolymers, designated T28 and T64, with the level of copolymer varying from 1 to 15 wt %,. All samples were prepared by solution blending in a 60/40 (by weight) phenol/tetrachloroethane solvent at 50degreesC. The crystallization behavior of the samples was studied by DSC. The results indicate that both T28 and T64 accelerated the crystallization rate of PET in a manner similar to that of a nucleating agent, The acceleration of PET crystallization rate was most pronounced in the PET/T64 blends with a maximum level at 5 wt % of T64. The melting temperatures for the blends are comparable to that of pure PET. The observed changes in crystallization behavior are explained by the effect of the physical state of the copolyester during PET crystallization as well as the amount of copolymer in the blends. (C) 2002 Wiley Periodicals, Inc. [References: 17]