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首页> 外文期刊>Journal of Applied Polymer Science >The Effects of p-Butoxyphenylcyclohexyl-phosphinic Acid on the Properties of PC Based on Bisphenol A
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The Effects of p-Butoxyphenylcyclohexyl-phosphinic Acid on the Properties of PC Based on Bisphenol A

机译:对丁氧基苯基环己基次膦酸对基于双酚A的PC性能的影响

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摘要

A polymer stabilizer, kp-butoxyphenylcyclohexyl-phosphinic acid, was introduced into an industrial polymer, a Bisphenol A-based polycarbonate, and the effects of this stabilizer on the mechanical and thermal properties were investigated. The mechanical properties were improved with small amount of stabilizers, while thermal properties were not effected significantly. For higher contents of stabilier, both thermal and mechanical properties were deteriorated. This deterioration was caused by the increase of molecular distance between the chains, which lead to the reduction of polar forces and an increase in the free volume of the polymer.
机译:将聚合物稳定剂kp-丁氧基苯基环己基次膦酸引入工业聚合物双酚A基聚碳酸酯中,并研究了该稳定剂对机械和热性能的影响。少量的稳定剂可改善机械性能,而热性能不会受到明显影响。对于更高含量的稳定剂,热性能和机械性能均下降。这种劣化是由于链之间的分子距离增加而引起的,这导致极性力的减小和聚合物的自由体积的增加。

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