5-2-（对苯偶氮苯氧基）丁氧基苯基-10,15,20-三（对甲氧基苯基）卟啉及其金属配合物的合成

摘要

以5-[2-(4-溴丁氧基)苯基]-10,15,20-三(对甲氧基苯基)卟啉和对羟基偶氮苯为原料,经取代反应合成新化合物5-[2-(对苯偶氮苯氧基)丁氧基]苯基-10,15,20-三[(对甲氧基苯基)]卟啉(2),2经配位反应合成了金属铜,锌配合物(2a)和(2b),其结构经 UV-Vis,1H NMR, IR和元素分析表征。%5-[2-(4-Para-phenylazophenyloxy) butoxy] phenyl-10,15,20- tri[(para-metoxyphenyl)] porphyrin were synthesized by substitution reaction of 5-[ ( 2-bromobutoxy ) ] phenyl-10 , 15 , 20-tri [ ( para-metoxy phenyl) ] porphyrin with para-hydroxyazobenzene. The copper(Ⅱ) and zinc(Ⅱ) ion complexes were synthesized via complexing reaction; The structures were characterized by UV-Vis, 1 H NMR, IR and elemental analysis.