Simultaneous determination of dihydroxybenzene isomers based on thionine functionalized multiwall carbon nanotubes modified electrode

摘要

In this article, simultaneous determination of dihydroxybenzene isomers [hydroquinone (HQ), catechol(CC), and resorcinol (RC)] was investigated using cyclic voltammetry (CV) and differential pulse voltammetry(DPV) at thionine functionalized multiwalled carbon nanotube (TH-MWCNTs) modified glass carbon electrode. CV and DPV results showed that the TH-MWCNTs modified electrode exhibited excellent recognition ability toward the three isomers of dihydroxybenzene. Their oxidize peak currents were linear over ranges from 9.0 9 10~(-7) to 3.6 9 10~(-4) M for HQ, from 3.3 9 10~(-6) to 8.1 9 10~(-4) M for CC and from 4.3 9 10~(-6) to 9.0 9 10~(-4) M for RC, with the detection limits of 2.7 9 10~(-7), 1.0 9 10~(-6), and 1.1 9 10~(-6) M, respectively. The proposed method would potentially be applied to multi-component analysis in environmental control and chemical industry.