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首页> 外文期刊>Journal de Physique, IV: Proceedings of International Conference >A study of morphology and texture of LPCVD germanium-silicon films
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A study of morphology and texture of LPCVD germanium-silicon films

机译:LPCVD锗硅薄膜的形貌和织构研究

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In this work, LPCVD Germanium-Silicon films were deposited on thermally oxidised silicon wafers using a horizontal LPCVD system, at a deposition temperature in the range between 430 and 480 ℃ and total pressure between 5 and 200 Pa. Pure GeH_4 and SiH_4 gases were used as precursors. Morphology and texture of the Ge_xSi_(1-x) (X = 0.3-0.6) films were investigated versus deposition parameters. It has been shown that at the deposition temperature of 430 ℃ and total pressure of 20 Pa the grain size varied between 40 and 80 nm for a <100-em thick poly-Ge_(0.6)Si_(0.4) film, and the root-mean-square surface roughness did not exceed 2.5 nm. A decrease of the Germanium content from 60 to 40 atomic percent caused an increase of both the grain size and surface roughness due to nucleation matters. The polycrystalline layers mainly contained (110)- and (111)-oriented grains with its ratio depending on both deposition pressure and film thickness. The appearance of the big grains and roughening of the surface was also observed with increasing film thickness. Rising the total pressure above a certain level (100-200 Pa) caused an enhanced formation of the amorphous phase and appearance of randomly situated surface convexities. Reducing the total pressure below 10 Pa led to roughening of the surface, probably due to a dominance of (111)-oriented grains in the film bulk at such a low pressure.
机译:在这项工作中,使用水平LPCVD系统在430至480℃的范围内,总压力在5至200 Pa的范围内,在水平氧化的硅晶片上沉积LPCVD锗硅膜。使用纯GeH_4和SiH_4气体作为先驱。研究了Ge_xSi_(1-x)(X = 0.3-0.6)薄膜的形貌和织构与沉积参数的关系。结果表明,对于厚度小于100em的多Ge_(0.6)Si_(0.4)膜,在430℃的沉积温度和20 Pa的总压力下,晶粒尺寸在40至80 nm之间变化,而根-均方根表面粗糙度不超过2.5 nm。锗含量从60原子百分比降低到40原子百分比会导致成核物质增加晶粒尺寸和表面粗糙度。多晶层主要包含(110)-和(111)-取向的晶粒,其比率取决于沉积压力和膜厚度。随着膜厚度的增加,还观察到大晶粒的出现和表面的粗糙化。将总压力提高到一定水平(100-200 Pa)以上会导致非晶相的形成增加,并出现随机分布的表面凸面。将总压力降低至10 Pa以下会导致表面粗糙,这可能是由于在如此低的压力下,薄膜主体中的(111)取向晶粒占优势。

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