New method of the directional modification of the electronic structure of single-walled carbon nanotubes by filling channels with metallic copper from a liquid phase

摘要

A method has been proposed and successfully implemented for filling the channels of single-walled carbon nanotubes with metallic copper by permeating with an aqueous solution of copper nitrate with subsequent thermal treatment. It has been demonstrated that the introduction of metallic copper into the channels of nanotubes leads to donor doping accompanied both by an increase in the Fermi energy of nanotubes and by the transfer of the electron density from introduced metal nanoparticles to the walls of nanotubes.