THERMAL REACTION OF 5-ARYL-6-TRIFLUOROMETHYL-3,6-DIHYDRO-2H-[1,3,4]OXADIAZINES ACCESSING 5-TRIFLUOROMETHYLIMIDAZOLS

Yasuhiro Kamitori; Tomoko Sekiyama; Etsuji Okada

首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >THERMAL REACTION OF 5-ARYL-6-TRIFLUOROMETHYL-3,6-DIHYDRO-2H-[1,3,4]OXADIAZINES ACCESSING 5-TRIFLUOROMETHYLIMIDAZOLS

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THERMAL REACTION OF 5-ARYL-6-TRIFLUOROMETHYL-3,6-DIHYDRO-2H-[1,3,4]OXADIAZINES ACCESSING 5-TRIFLUOROMETHYLIMIDAZOLS

机译：5-芳基-6-三氟甲基-3,6-二氢-2H- [1,3,4]恶二嗪与5-三氟甲基咪唑反应的热反应

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Thermal reaction of 5-aryl-6-trifluoromethyl-3,6-dihydro-2H-[1,3,4]oxadiazines (2) readily obtainable from 3-aryl-3-dimethylhydrazono-1,1,1-trifluoro-2-propanones (1) afforded 4-aryl-1-methyl-5-trifluoromethyl-imidazoles (3) in moderate to good yields.Mechanism for this thermal transformation reaction is also discussed.

机译：5-芳基-6-三氟甲基-3,6-二氢-2H- [1,3,4]恶二嗪（2）的热反应可从3-芳基-3-二甲基hydr基-1,1,1-三氟-2轻松获得-丙烷（1）以中等至良好的产率提供了4-芳基-1-甲基-5-三氟甲基-咪唑（3）。还讨论了该热转化反应的机理。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry 》 |2007年第0期| 共6页
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Yasuhiro Kamitori; Tomoko Sekiyama; Etsuji Okada;
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1. THERMAL REACTION OF 5-ARYL-6-TRIFLUOROMETHYL-3,6-DIHYDRO-2H-[1,3,4]OXADIAZINES ACCESSING 5-TRIFLUOROMETHYLIMIDAZOLS [J] . Yasuhiro Kamitori, Tomoko Sekiyama, Etsuji Okada Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2007 ,第0期

机译：5-芳基-6-三氟甲基-3,6-二氢-2H- [1,3,4]恶二嗪与5-三氟甲基咪唑反应的热反应
2. ACID CATALYZED CYCLIZATION REACTION OF 3-HYDRAZONO-1,1,1-TRIFLUORO-2-ALKANONES TO 6-TRIFLUOROMETHYL-3,6-DIHYDRO-2H-[1,3,4]OXADIAZINES [J] . Yasuhiro Kamitori, Tomoko Sekiyama Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2005 ,第9期

机译：3-Hydrazono-1,1,1-trifluoro-2-alkanones到6-trifluromethyl-3,6-DiHYDRO-2H- [1,3,4] OXADIAZINES的酸催化循环反应
3. REACTION OF 3-HYDRAZONO-1,1,1-TRIFLUORO-2-ALKANONES WITH LAWESSON REAGENT ACCESSING 6-TRIFLUOROMETHYL-3,6-DIHYDRO-2H-[1,3,4]THIADIAZINES [J] . Yasuhiro Kamitori, Tomoko Sekiyama, Etsuji Okada Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2007 ,第10期

机译：3-Hydrazono-1,1,1-trifluoro-2-alkanenes与Lawson试剂反应6-Fluoromethyl-3,6-DiHYDRO-2H- [1,3,4]噻二嗪的反应
4. Synthesis, Structural, Thermal and Hirshfeld Surface Analysis of Novel 1,2,4triazolo3,4-b1,3,4 thiadiazine Carrying 1,4-Benzothiazine-3-one Moiety [C] . C. Shruthi, V. Ravindrachary, B. Guruswamy, International Conference on Condensed Matter and Applied Physics . 2017

机译：新颖的合成，结构，热和Hirshfeld表面分析1,2,4三唑3,4-b 1,3,4噻二嗪携带1,4-苯并噻嗪-3-一部分
5. Part I: 1,3,4-oxadiazoles in tandem Diels-Alder, 1,3-dipolar cycloaddition reactions: A rapid synthesis of vinca alkaloid motifs. Part II: Exceptionally potent inhibitors of fatty acid amide hydrolase [D] . Wilkie, Gordon David 2002

机译：第一部分：串联Diels-Alder中的1,3,4-恶二唑，1,3-偶极环加成反应：长春花生物碱基序的快速合成。第二部分：脂肪酸酰胺水解酶的超强抑制剂
6. Thermal studies of the rates of the reactions of carbon dioxide in concentrated haemoglobin solutions and in red blood cells. A. The reactions catalysed by carbonic anhydrase. B. The carbamino reactions of oxygenated and deoxygenated haemoglobin [O] . J. C. Kernohan, F. J. W. Roughton 1968

机译：对浓缩血红蛋白溶液和红细胞中二氧化碳反应速率的热研究。 A.由碳酸酐酶催化的反应。 B.氧化的和脱氧的血红蛋白的氨基甲酸酯反应
7. Conjugated and Nonconjugated Cyclopentenones by a Reaction Cascade from Methyl 6-0xo-5-phenyl-1,3,4-oxadiazine-2-carboxylate and 1,3-Butadienes [O] . Hegmann Joachim, Christl Manfred, Peters Karl, 2008

机译：6-0xo-5-苯基-1,3,4-恶二嗪-2-羧酸甲酯和1,3-丁二烯的反应级联反应产生的共轭和非共轭环戊烯酮

THERMAL REACTION OF 5-ARYL-6-TRIFLUOROMETHYL-3,6-DIHYDRO-2H-[1,3,4]OXADIAZINES ACCESSING 5-TRIFLUOROMETHYLIMIDAZOLS

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