PYRIDINE-DERIVED HETEROCYCLES AS POTENTIAL PHOTOACYLATING REAGENTS

摘要

We prepared several pyridine-derived heterocycles and investigated their photoacylating properties.Among representatives of 4 families of compounds(1-acetyl-7-azaindole,1-acetyl-7-azaindoline,2-acetamindpyridine and 2-amidopyrimidines),the 2-aminopyrimidine derivatives were the most promising candidates.Photoacylation of dodecylamine yields up to 47% were obtained,upon irradiation with UV light at 254 nm.