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Metal Extraction from Nitric Acid Solutions by the Macrocyclic Endoreceptor Dicyclohexyl-18-Crown-6 Immobilized in a Polymer Matrix

机译:固定在聚合物基体中的大环内受体二环己基-18-Crown-6从硝酸溶液中金属萃取

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摘要

Macrocyclic endoreceptors (MEs) form stable adducts with metal salts (substrates) if they are complementary in spatial structure and energy characteristics [1]. These features are used in the extraction recovery and separation of elements with similar chemical properties [2]. Metal extraction from solutions in nitric acid using dicyclohexyl-18-crown-6 (DCH18C6) in organic solvents has been studied most extensively [3].
机译:如果大环内受体(MEs)在空间结构和能量特征上互补,它们会与金属盐(底物)形成稳定的加合物[1]。这些特征用于具有相似化学性质的元素的萃取回收和分离[2]。在有机溶剂中使用二环己基-18-冠-6(DCH18C6)从硝酸溶液中萃取金属的方法已得到最广泛的研究[3]。

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