Synthesis, X-ray crystal structure and optical properties of novel 2,5-diaryl-l, 3,4-oxadiazole derivatives containing substituted pyrazolo[l,5-a]pyridine units

摘要

A series of pyrazolo[l,5-a]pyridine-containing 2,5-diaryI-l,3,4-oxadiazole derivatives were synthesized and their structures were characterized by 1R, ~1H NMR and HRMS spectra. The crystal structure of 3a was determined using single crystal X-ray crystallography. Its spatial structure was found to be monoclinic, and all aromatic rings were approximately coplanar, which allowed conjugation. The absorption results showed that compounds 1a-f presented their absorption peaks ranging from 264 nm to 290 nm, while compounds 3a—f with a larger conjugation system exhibited red-shifted absorption character (absorption maxima between 283 nm and 303 nm) compared to the corresponding absorption of 1a-f. Fluorescence spectra revealed that these compounds exhibited blue fluorescence (421-444 nm) in dilute solutions and showed quantum yields of fluorescence between 0.32 and 0.83 in dichloromethane.