Spirosilabifluorene linked bistriphenylamine:Synthesis and application in hole transporting and two-photon fluorescent imaging

摘要

Spirosila-BF-TPA,in which two identical triphenylamines linked orthogonally around a spirosilabifluorene core,has been synthesized and characterized.The introduction of a spiro linkage into the structure of spirosila-BF-TPA leads to a reduction in crystallization tendency and no glass transition temperature was observed.Spirosila-BF-TPA exhibits blue emission around 410 nm.Its reversible electrochemical oxidation and low ionization potential (5.33 eV)suggest that spirosila-BF-TPA might have potential application as a hole transporting material.The hole transport ability of spirosila-BF-TPA was tested by comparing the performance of the two types of OLED devices.According to the fluorescence images of spirosila-BF-TPA films,it was found that the two-photon fluorescence of spirosila-BF-TPA is intensive,which implies that this molecule is also a promising candidate for an application such as two-photon microscopy and imaging.